Pillar[5]arene decaamine: synthesis, encapsulation of very long linear diacids and formation of ion pair-stopped [2]rotaxanes.

نویسندگان

  • Xiao-Bo Hu
  • Lei Chen
  • Wen Si
  • Yihua Yu
  • Jun-Li Hou
چکیده

A pillar[5]arene decaamine has been synthesized and revealed to encapsulate linear diacids in neutral, alkaline, and acidic conditions, driven by the hydrophobic and electrostatic interactions, to give rise to pseudo[2]rotaxanes. Ion pair-bonded stoppers can further lock the diacids to generate stable water soluble [2]rotaxanes.

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عنوان ژورنال:
  • Chemical communications

دوره 47 16  شماره 

صفحات  -

تاریخ انتشار 2011